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Ruthenium-catalyzed asymmetric transfer hydrogenation of ketones in ethanol
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
2011 (English)Conference paper, Published paper (Other academic)
Abstract [en]

A ruthenium catalyst formed in situ by combining [Ru(p-cymene)Cl2]2 and an amino acid hydroxy-amide was found to catalyze efficiently the asymmetric reduction of aryl alkyl ketones under transfer hydrogenation conditions using ethanol as the hydrogen donor. The secondary alcohol products were obtained in moderate to good yields and with good to excellent enantioselectivity (up to 97% ee).

Place, publisher, year, edition, pages
2011.
National Category
Organic Chemistry
Identifiers
URN: urn:nbn:se:su:diva-62967OAI: oai:DiVA.org:su-62967DiVA: diva2:446149
Conference
242nd ACS national meeting, Denver, CO, USA
Available from: 2011-10-06 Created: 2011-10-06Bibliographically approved

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Lundberg, HelenaAdolfsson, Hans
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