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Carbohydrate-based pseudo-dipeptides: new ligands for the highly enantioselective Ru-catalyzed transfer hydrogenation reaction
Stockholm University, Faculty of Science, Department of Organic Chemistry.
2011 (English)In: Chemical Communications, ISSN 1359-7345, E-ISSN 1364-548X, Vol. 47, no 44, 12188-12190 p.Article in journal (Refereed) Published
Abstract [en]

Ruthenium-complexes of novel carbohydrate based pseudo-dipeptide ligands effectively and selectively catalyze the reduction of a broad range of aryl–alkyl ketones under ATH conditions. Excellent enantioselectivities (>99% ee) are obtained using aminosugars as the sole source of chirality.

Place, publisher, year, edition, pages
The Royal Society of Chemistry , 2011. Vol. 47, no 44, 12188-12190 p.
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Organic Chemistry
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URN: urn:nbn:se:su:diva-64126DOI: 10.1039/c1cc15024cISI: 000296342800047OAI: oai:DiVA.org:su-64126DiVA: diva2:455341
Funder
Swedish Research Council
Available from: 2011-11-09 Created: 2011-11-09 Last updated: 2017-12-08Bibliographically approved

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