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Investigation of Coupling Reactions for the Synthesis of Valienamine Pseudodisaccharides
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
2011 (English)In: Synlett: Accounts and Rapid Communications in Synthetic Organic Chemistry, ISSN 0936-5214, E-ISSN 1437-2096, no 12, 1701-1704 p.Article in journal (Refereed) Published
Abstract [en]

Amine-linked pseudodisaccharides based on valienamine were synthesised by C-N bond-forming reactions between valienol-derived C-1 electrophiles and carbohydrate nitrogen nucleophiles. Palladium-catalysed coupling with trichloroacetimidate leaving groups, Mitsunobu reactions with a nosylamide nucleophile, and alkylation of amines by C-1 bromides were investigated.

Place, publisher, year, edition, pages
2011. no 12, 1701-1704 p.
Keyword [en]
amination, carbohydrates, carbocycles, pseudodisaccharides, valienamine
National Category
Organic Chemistry
Identifiers
URN: urn:nbn:se:su:diva-66983DOI: 10.1055/s-0030-1260801ISI: 000292596600012OAI: oai:DiVA.org:su-66983DiVA: diva2:470071
Note
authorCount :3Available from: 2011-12-28 Created: 2011-12-22 Last updated: 2017-12-08Bibliographically approved

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