Conversion of fructose into a building block for the synthesis of carbocyclic mannose mimics
2011 (English)In: Tetrahedron: asymmetry, ISSN 0957-4166, E-ISSN 1362-511X, Vol. 22, no 4, 399-405 p.Article in journal (Refereed) Published
Fructose was converted into C-1 diastereomeric carbocyclic building blocks resembling mannose using ruthenium-catalysed ring-closing metathesis as a key step. The potential use of the compounds in the synthesis of valienamine pseudodisaccharides is demonstrated using Mitsunobu coupling chemistry directly between a carbohydrate sulfonamide and the carbasugar C-1 alcohols.
Place, publisher, year, edition, pages
2011. Vol. 22, no 4, 399-405 p.
Inorganic Chemistry Organic Chemistry Physical Chemistry
IdentifiersURN: urn:nbn:se:su:diva-67914DOI: 10.1016/j.tetasy.2011.02.013ISI: 000290075100005OAI: oai:DiVA.org:su-67914DiVA: diva2:471901
authorCount :32012-01-032012-01-022012-01-03Bibliographically approved