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Hot Water from Cold. The Dissociative Recombination of Water Cluster Ions
Stockholm University, Faculty of Science, Department of Physics.
Stockholm University, Faculty of Science, Department of Physics.
Stockholm University, Faculty of Science, Department of Physics.
Stockholm University, Faculty of Science, Department of Physics.
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2010 (English)In: Journal of Physical Chemistry A, ISSN 1089-5639, E-ISSN 1520-5215, Vol. 114, no 14, 4843-4846 p.Article in journal (Refereed) Published
Abstract [en]

Dissociative recombination of the Zundel cation D(5)O(2)(+) almost exclusively produces D + 2 D(2)O with a maximum kinetic energy release of 5.1 eV. An imaging technique is used to investigate the distribution of the available reaction energy among these products. Analysis shows that as much as 4 eV can be stored internally by the molecular fragments, with a preference for producing highly excited molecular fragments, and that the deuteron shows a nonrandom distribution of kinetic energies. A possible mechanism and the implications for these observations are addressed.

Place, publisher, year, edition, pages
2010. Vol. 114, no 14, 4843-4846 p.
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Natural Sciences
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URN: urn:nbn:se:su:diva-68204DOI: 10.1021/jp9095979ISI: 000276341300021OAI: oai:DiVA.org:su-68204DiVA: diva2:472052
Note
authorCount :15Available from: 2012-01-03 Created: 2012-01-03 Last updated: 2017-12-08Bibliographically approved

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Zhaunerchyk, VitaliHellberg, FredrikEhlerding, AnneliGeppert, Wolf D.
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