Iridium-catalysed condensation of alcohols and amines as a method for aminosugar synthesis
2011 (English)In: Chemical Communications, ISSN 1359-7345, E-ISSN 1364-548X, Vol. 47, no 27, 7827-7829 p.Article in journal (Refereed) Published
Primary carbohydrate amines at primary and secondary carbons are alkylated by alcohols in the presence of [Cp*IrCl2]2. When primary carbohydrate alcohols are used as the coupling partners and in the presence of Cs2CO3, amine-linked pseudodisaccharides are obtained. Secondary carbohydrate alcohols are unaffected under these conditions, which allows regioselective reactions.
Place, publisher, year, edition, pages
2011. Vol. 47, no 27, 7827-7829 p.
IdentifiersURN: urn:nbn:se:su:diva-69710DOI: 10.1039/c1cc12800kISI: 000292113700079OAI: oai:DiVA.org:su-69710DiVA: diva2:478005
FunderSwedish Research Council
authorCount :42012-01-152012-01-152012-02-01Bibliographically approved