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Iridium-catalysed condensation of alcohols and amines as a method for aminosugar synthesis
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
2011 (English)In: Chemical Communications, ISSN 1359-7345, E-ISSN 1364-548X, Vol. 47, no 27, 7827-7829 p.Article in journal (Refereed) Published
Abstract [en]

Primary carbohydrate amines at primary and secondary carbons are alkylated by alcohols in the presence of [Cp*IrCl2]2. When primary carbohydrate alcohols are used as the coupling partners and in the presence of Cs2CO3, amine-linked pseudodisaccharides are obtained. Secondary carbohydrate alcohols are unaffected under these conditions, which allows regioselective reactions.

Place, publisher, year, edition, pages
2011. Vol. 47, no 27, 7827-7829 p.
National Category
Organic Chemistry
Identifiers
URN: urn:nbn:se:su:diva-69710DOI: 10.1039/c1cc12800kISI: 000292113700079OAI: oai:DiVA.org:su-69710DiVA: diva2:478005
Funder
Swedish Research Council
Note
authorCount :4Available from: 2012-01-15 Created: 2012-01-15 Last updated: 2017-12-08Bibliographically approved

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Agrawal, SantoshBorbas, K. EszterMartín-Matute, Belén
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