Cyclotricatechylene based porous crystalline material: Synthesis and applications in gas storage
2012 (English)In: Journal of Materials Chemistry, ISSN 0959-9428, E-ISSN 1364-5501, Vol. 22, no 12, 5369-5373 p.Article in journal (Refereed) Published
An undulated two-dimensional CTC-based covalent organic framework, CTC-COF, was synthesized through solvothermal reaction for the first time. This mesoporous material stacks in an eclipsed mode in the microcrystalline state. CTC-COF has a surface area of 1710 m(2) g(-1), with a pore width of 2.26 nm calculated by the NL-DFT modelling. The bowl-shaped core unit led to a larger surface area than its analogue, COF-5 constructed by planar subunits. This material has higher low pressure hydrogen uptake than other 2D COFs with similar structures, and even close to the 3D COF materials.
Place, publisher, year, edition, pages
2012. Vol. 22, no 12, 5369-5373 p.
IdentifiersURN: urn:nbn:se:su:diva-76753DOI: 10.1039/c2jm15159fISI: 000300838100019OAI: oai:DiVA.org:su-76753DiVA: diva2:527195