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A novel 1D independent metal-organic nanotube based on cyclotriveratrylene ligand
Stockholm University, Faculty of Science, Department of Materials and Environmental Chemistry (MMK), Inorganic and Structural Chemistry.
2012 (English)In: CrystEngComm, ISSN 1466-8033, E-ISSN 1466-8033, Vol. 14, no 1, 112-115 p.Article in journal (Refereed) Published
Abstract [en]

A novel nanotubular metal-organic framework [Cu3L2(EtOH)(Py)(2)(H2O)(2)]center dot 9DEF center dot 8H(2)O (CTV-Cu) was prepared by assembly of the rigid, trigonal pyramidal ligand tri-(4-carboxy-phenyl)-trimethoxycyclobenzylene (H3L) and Cu(NO3)(2)center dot 3H(2)O via solvothermal reaction. The Cu(II) ions in the crystal serve as square and linear molecular building blocks, thus forming a framework with ternary topology. One single open-ended nanotube contains two identical orthogonally interpenetrated two-nodal nets. This framework exhibits permanent microporosity and relatively high surface area.

Place, publisher, year, edition, pages
2012. Vol. 14, no 1, 112-115 p.
National Category
Inorganic Chemistry
Identifiers
URN: urn:nbn:se:su:diva-76747DOI: 10.1039/c1ce05316gISI: 000300617000019OAI: oai:DiVA.org:su-76747DiVA: diva2:527204
Note
4Available from: 2012-05-18 Created: 2012-05-16 Last updated: 2017-12-07Bibliographically approved

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