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Combined Enzyme and Transition-Metal Catalysis for Dynamic Kinetic Resolutions
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.ORCID iD: 0000-0002-7898-317X
2012 (English)In: Israel Journal of Chemistry, ISSN 0021-2148, Vol. 52, no 7, 639-652 p.Article, review/survey (Refereed) Published
Abstract [en]

The preparation of optically pure alcohols, axially chiral allenes, and amine derivatives by using enzymes and transition-metal catalysts through dynamic kinetic resolution (DKR) is reviewed. After a general introduction into enzymatic kinetic resolutions and racemizations catalyzed by transition-metal complexes, selected examples of DKRs are presented, from early work to more recent outstanding contributions, and also applications of this approach.

Place, publisher, year, edition, pages
2012. Vol. 52, no 7, 639-652 p.
Keyword [en]
DKR, enzymes, kinetic resolution, racemization, transition metals
National Category
Chemical Sciences
Identifiers
URN: urn:nbn:se:su:diva-80425DOI: 10.1002/ijch.201200012ISI: 000306510700009OAI: oai:DiVA.org:su-80425DiVA: diva2:556178
Funder
Swedish Research CouncilWenner-Gren FoundationsBerzelii Centre EXSELENT
Note

AuthorCount:2;

Available from: 2012-09-24 Created: 2012-09-19 Last updated: 2017-11-10Bibliographically approved

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Marcos, RocioMartín-Matute, Belén
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