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Methyl 3-O-α-l-fucopyranosyl β-d-glucopyranoside tetrahydrate
Stockholm University, Faculty of Science, Department of Materials and Environmental Chemistry (MMK).
Stockholm University, Faculty of Science, Department of Organic Chemistry.
2012 (English)In: Acta Crystallographica Section E: Structure Reports Online, ISSN 1600-5368, E-ISSN 1600-5368, Vol. 68, o3180-o3181 p.Article in journal (Refereed) Published
Abstract [en]

The title compound, C13H24O10·4H2O, is the methyl glycoside of a disaccharide structural element present in the backbone of the capsular polysaccharide from Klebsiella K1, which contains only three sugars and a substituent in the polysaccharide repeating unit. The conformation of the title disaccharide is described by the glycosidic torsion angles ϕH = 51.1 (1)° and ψH = 25.8 (1)°. In the crystal, a number of O—HO hydrogen bonds link the methyl glycoside and water mol­ecules, forming a three-dimensional network. One water mol­ecule is disordered over two positions with occupancies of 0.748 (4) and 0.252 (4).

Place, publisher, year, edition, pages
2012. Vol. 68, o3180-o3181 p.
National Category
Organic Chemistry
Identifiers
URN: urn:nbn:se:su:diva-85930DOI: 10.1107/S1600536812041992OAI: oai:DiVA.org:su-85930DiVA: diva2:585538
Funder
Swedish Research Council
Available from: 2013-01-10 Created: 2013-01-10 Last updated: 2017-12-06Bibliographically approved

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Eriksson, LarsWidmalm, Göran
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