Palladium-Catalyzed Oxidative Diarylating Carbocyclization of Enynes
2012 (English)In: Organic Letters, ISSN 1523-7060, E-ISSN 1523-7052, Vol. 14, no 13, 3538-3541 p.Article in journal (Refereed) Published
A mild and efficient palladium-catalyzed oxidative diarylating carbocyclization of enynes is described. The reaction tolerates a range of functionalized arylboronic acids to give diarylated products in good yields. Control experiments suggest that the reaction starts with an arylpalladation of the alkyne, followed by carbocyclization, transmetalation, and reductive elimination to afford the diarylated product.
Place, publisher, year, edition, pages
2012. Vol. 14, no 13, 3538-3541 p.
Research subject Organic Chemistry
IdentifiersURN: urn:nbn:se:su:diva-86241DOI: 10.1021/ol301551xISI: 000306050300077OAI: oai:DiVA.org:su-86241DiVA: diva2:586517
FunderSwedish Research CouncilEU, European Research Council, ERC AdG247014