Molecular Single-site Ruthenium Complexes Containing a Basic Site: The Use of Structure-activity Relationships
(English)Manuscript (preprint) (Other academic)
A series of single-site ruthenium(III) complexes (2a-d) were synthesized and characterized, and employed in the oxidation of H2O. A linear free-energy relationship study was conducted in order to establish a correlation between the electrochemical properties and the electronic parameters of the introduced substituents in complexes 2a-d.
water oxidation, transition metal catalysis, ruthenium
Research subject Organic Chemistry
IdentifiersURN: urn:nbn:se:su:diva-86766OAI: oai:DiVA.org:su-86766DiVA: diva2:589327