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Pincer complexes as catalysts in organic chemistry
Stockholm University, Faculty of Science, Department of Organic Chemistry.
2013 (English)In: Organometallic pincer chemistry / [ed] VanKoten, G., Milstein, D., Berlin, Heidelberg: Springer Berlin/Heidelberg, 2013, 203-241 p.Chapter in book (Refereed)
Abstract [en]

Application of pincer complexes in catalytic applications is a rapidly expanding field in organic synthesis. This chapter is mainly focused on selective formation of carbon carbon, carbon nitrogen, and carbon metal (C B, C Si, and S-Sn) bonds, as well as transfer hydrogenation reactions. The described pincer-complex catalyzed processes are more efficient and more selective than the corresponding transformations catalyzed by metal salts and added ligands. Some of the described pincer-complex catalyzed reactions are not amenable by traditional metal catalysts at all. It has been demonstrated that the superiority of pincer-complex catalysts over the traditional ones is based on the high stability and well-defined structure and stoichiometry of these species. These properties of pincer complexes allow a rational design of active and highly selective catalysts.

Place, publisher, year, edition, pages
Berlin, Heidelberg: Springer Berlin/Heidelberg, 2013. 203-241 p.
Series
Topics in Organometallic Chemistry, ISSN 1436-6002 ; 40
Keyword [en]
Aldol reaction, Allylation, Hydrogenation, Michael addition, Palladium, Pincer complexes, Rhodium, Ruthenium
National Category
Chemical Sciences
Identifiers
URN: urn:nbn:se:su:diva-88305DOI: 10.1007/978-3-642-31081-2_7ISI: 000312747200007ISBN: 978-3-642-31081-2 (print)OAI: oai:DiVA.org:su-88305DiVA: diva2:611901
Note

AuthorCount:1;

Available from: 2013-03-19 Created: 2013-03-12 Last updated: 2013-10-07Bibliographically approved

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