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Two Isomeric Magnesium Metal-Organic Frameworks with [24-MC-6] Metallacrown Cluster
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2013 (English)In: Crystal Growth & Design, ISSN 1528-7483, E-ISSN 1528-7505, Vol. 13, no 5, 1807-1811 p.Article in journal (Refereed) Published
Abstract [en]

Two novel Mg-based metal-organic framework isomers with the formula [Mg-2(HCO2)(2)(NH2-BDC)-(DMF)(2)](n) (NH2-BDC = 2-amino-1,4-benzenedicarboxylate) have been synthesized based on a 6-connected [24-MC-6] metallacrown secondary building unit (SBU), which display a two-dimensional (2D) 3(6) net (1) and three-dimensional primitive rhombohedral net (2) derived from a different extended orientation of SBU, respectively. The 2D framework of 1 exhibits relevant thermal stability, solvents stability, high CO2 adsorption, and strong luminescent properties.

Place, publisher, year, edition, pages
2013. Vol. 13, no 5, 1807-1811 p.
National Category
Chemical Sciences Materials Chemistry
URN: urn:nbn:se:su:diva-91042DOI: 10.1021/cg4000318ISI: 000318468400002OAI: diva2:630483
Swedish Research Council


Available from: 2013-06-19 Created: 2013-06-18 Last updated: 2013-06-19Bibliographically approved

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Sun, JunliangZou, Xiaodong
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Department of Materials and Environmental Chemistry (MMK)
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