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Isotope shift on the chlorine electron affinity revisited by an MCHF/CI approach
Stockholm University, Faculty of Science, Department of Physics. University Libre Brussels .
2013 (English)In: Journal of Physics B: Atomic, Molecular and Optical Physics, ISSN 0953-4075, E-ISSN 1361-6455, Vol. 46, no 9, 095003- p.Article in journal (Refereed) Published
Abstract [en]

Today, the electron affinity is experimentally well known for most of the elements and is a useful guideline for developing ab initio computational methods. However, the measurements of isotope shifts on the electron affinity are limited by both resolution and sensitivity. In this context, theory is of great help to further our knowledge and understanding of atomic structures, even though correlation plays a dominant role in negative ions' properties and, particularly, in the calculation of the specific mass shift contribution. This study solves the longstanding discrepancy between calculated and measured specific mass shifts on the electron affinity of chlorine.

Place, publisher, year, edition, pages
2013. Vol. 46, no 9, 095003- p.
National Category
Atom and Molecular Physics and Optics
Identifiers
URN: urn:nbn:se:su:diva-91195DOI: 10.1088/0953-4075/46/9/095003ISI: 000318070800003OAI: oai:DiVA.org:su-91195DiVA: diva2:632052
Note

AuthorCount:2;

Available from: 2013-06-24 Created: 2013-06-24 Last updated: 2017-12-06Bibliographically approved

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