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Synthesis and fading of eighteenth-century Prussian blue pigments: a combined study by spectroscopic and diffractive techniques using laboratory and synchrotron radiation sources
Stockholm University, Faculty of Science, Department of Materials and Environmental Chemistry (MMK), Inorganic and Structural Chemistry. Univ Liege, Ctr Europeen Archeometrie, Belgium.
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2013 (English)In: Journal of Synchrotron Radiation, ISSN 0909-0495, E-ISSN 1600-5775, Vol. 20, 460-473 p.Article in journal (Refereed) Published
Abstract [en]

Prussian blue, a hydrated iron(III) hexacyanoferrate(II) complex, is a synthetic pigment discovered in Berlin in 1704. Because of both its highly intense color and its low cost, Prussian blue was widely used as a pigment in paintings until the 1970s. The early preparative methods were rapidly recognized as a contributory factor in the fading of the pigment, a fading already known by the mid-eighteenth century. Herein two typical eighteenth-century empirical recipes have been reproduced and the resulting pigment analyzed to better understand the reasons for this fading. X-ray absorption and Mossbauer spectroscopy indicated that the early syntheses lead to Prussian blue together with variable amounts of an undesirable iron(III) product. Pair distribution functional analysis confirmed the presence of nanocrystalline ferrihydrite, Fe10O14(OH)(2), and also identified the presence of alumina hydrate, Al10O14(OH)(2), with a particle size of similar to 15 angstrom. Paint layers prepared from these pigments subjected to accelerated light exposure showed a tendency to turn green, a tendency that was often reported in eighteenth- and nineteenth-century books. The presence of particles of hydrous iron(III) oxides was also observed in a genuine eighteenth-century Prussian blue sample obtained from a polychrome sculpture.

Place, publisher, year, edition, pages
2013. Vol. 20, 460-473 p.
Keyword [en]
iron(III) hexacyanoferrate(II), archaeometry, pair distribution function, light exposure fading, paint layers
National Category
Physical Sciences
URN: urn:nbn:se:su:diva-91304DOI: 10.1107/S0909049513004585ISI: 000317604800010OAI: diva2:633501


Available from: 2013-06-27 Created: 2013-06-24 Last updated: 2013-06-27Bibliographically approved

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Samain, Louise
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