Aims. The Sagittarius A complex in the Galactic centre comprises an ensemble of molecular clouds of different species with a variety of geometrical and kinematic properties. This work aims to study molecular abundances, morphology, and kinematics by comparing hydroxyl, water, carbon monoxide, ammonia, and atomic carbon and some of their isotopologues, in the +50 km s(-1) cloud, the circumnuclear disk (CND), the +20 km s(-1) cloud, the expanding molecular ring and the line-of-sight spiral arm features, including the Local/Sgr arm, the -30 km s(-1) arm, and the 3-kpc arm. Methods. We observed the +50 km s(-1) cloud, the CND and the +20 km s(-1) cloud, and other selected positions at the Galactic centre with the VLA, and the Odin satellite. The VLA was used to map the 1665 and 1667 MHz OH lambda doublet main lines of the (H-2(3/2)) state, and the Odin satellite was used to map the 557 GHz H2O (1(10)-1(01)) line as well as to observe the 548 GHz (H2O)-O-18 (1(10)-1(01)) line, the 572 GHz NH3 (1(0)-0(0)) line, the 576 GHz CO J = 5-4 line and the 492 GHz C-I (P-3(1)-P-3(0)) line. Furthermore, the SEST was used to map a 4'.5 x 6' region of the SgrAcomplex in the 220 GHz (CO)-O-18 J = 2-1 line. Results. Strong OH absorption, H2O emission and absorption lines were seen at all observed positions, and the (H2O)-O-18 line was detected in absorption towards the +50 km s(-1) cloud, the CND, the +20 km s(-1)cloud, the expanding molecular ring, and the 3-kpc arm. Strong CO J = 5-4, (CO)-O-18 J = 2-1, and neutral carbon C-I emissions were seen towards the +50 and +20 km s(-1) clouds. NH3 was only detected in weak absorption originating in the line-of-sight spiral arm features. The abundances of OH and H2O in the +50 and +20 km s(-1) clouds reflect the different physical environments in the clouds, where shocks and star formation prevail in the +50 km s(-1) cloud and giving rise to a higher rate of H2O production there than in the +20 km s(-1) cloud. In the CND, cloud collisions and shocks are frequent, and the CND is also subject to intense UV-radiation emanating from the supermassive black hole and the central star cluster. The CND is rich in (HO)-O-2 and OH, and these abundances are considerably higher than in the +50 and +20 km s(-1) clouds. We compare our estimated abundances of OH, H2O, and NH3 with similar and differing results for some other sources available in the literature. As compared to the quiescent cloud values of a few x 10(-9), or lower, the H2O abundance is markedly enhanced in the front sides of the Sgr A molecular cloud cores, (2-7) x 10(-8), as observed in absorption, and highest in the CND. A similar abundance enhancement is seen in OH. The likely explanation is PDR chemistry including grain surface reactions, and perhaps also the influence of shocks. In the redward high-velocity line wings of the +50 and +20 km s(-1) clouds and the CND, the H2O abundances are estimated to be (1-6) x 10(-6) or higher, i.e., similar to the water abundances in outflows of the Orion KL and DR21 molecular clouds, which are said to be caused by the combined action of shock desorption from icy grain mantles and high-temperature, gas-phase shock chemistry.
2013. Vol. 554, A141