Change search
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf
Enantioselective Dehydrochlorination of δ-Hexachlorocyclohexane and δ-Pentachlorocyclohexene by LinA1 and LinA2 from Sphingobium indicum B90A
Department of Environmental Microbiology, Swiss Federal Institute for Aquatic Science and Technology (Eawag), Dübendorf, Switzerland.
Department of Environmental Microbiology, Swiss Federal Institute for Aquatic Science and Technology (Eawag), Dübendorf, Switzerland.
Agroscope Changins-Wädenswil, Research Station ACW, Wädenswil, Switzerland.
Laboratory for Functional Polymers, Swiss Federal Laboratories for Materials Science and Technology (EMPA), Dübendorf, Switzerland.
Show others and affiliations
2013 (English)In: Applied and Environmental Microbiology, ISSN 0099-2240, E-ISSN 1098-5336, Vol. 79, no 19, 6180-6183 p.Article in journal (Refereed) Published
Abstract [en]

ÎŽ-Hexachlorocyclohexane (ÎŽ-HCH), one of the prevalent isomers of technical HCH, was enantioselectively dehydrochlorinated by the dehydrochlorinases LinA1 and LinA2 from Sphingobium indicum B90A to the very same ÎŽ-pentachlorocyclohexene enantiomer. Racemic ÎŽ-pentachlorocyclohexene, however, was transformed with opposite enantioselectivities by the two enzymes. A transformation pathway based on an anti-1,2-elimination, followed by a syn-1,4-elimination and a subsequent syn-1,2-elimination is postulated.

Place, publisher, year, edition, pages
2013. Vol. 79, no 19, 6180-6183 p.
National Category
Environmental Sciences
Identifiers
URN: urn:nbn:se:su:diva-94607DOI: 10.1128/AEM.01770-13PubMedID: 23872559OAI: oai:DiVA.org:su-94607DiVA: diva2:653990
Available from: 2013-10-07 Created: 2013-10-07 Last updated: 2017-12-06Bibliographically approved

Open Access in DiVA

No full text

Other links

Publisher's full textPubMed

Search in DiVA

By author/editor
Miska, Milena E.
In the same journal
Applied and Environmental Microbiology
Environmental Sciences

Search outside of DiVA

GoogleGoogle Scholar

doi
pubmed
urn-nbn

Altmetric score

doi
pubmed
urn-nbn
Total: 22 hits
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf