Change search
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf
Structural characterization of Sr4Mg4H4[CoH5](3) shows the importance of support from polarizing counter ions to 3d transition metal hydrido complexes
Stockholm University, Faculty of Science, Department of Materials and Environmental Chemistry (MMK).
Stockholm University, Faculty of Science, Department of Materials and Environmental Chemistry (MMK).
Stockholm University, Faculty of Science, Department of Materials and Environmental Chemistry (MMK).
2013 (English)In: Journal of Alloys and Compounds, ISSN 0925-8388, E-ISSN 1873-4669, Vol. 579, 31-33 p.Article in journal (Refereed) Published
Abstract [en]

The structure of the title compound was refined from neutron powder diffraction data in the cubic space group P-43m (215). The unit cell contains one formula unit with 3 structurally equivalent [Co(I)H-5](4)-complexes as well as 4 interstitial hydride (H-) ions. The presence of the larger and less polarizing Sr2+ ions weakens the bond in the complexes and probably also the stability of the structure. Attempts to synthesize the corresponding Ba analogue failed in contrast to using smaller and more polarizing Ca2+ and Yb2+ counterions.

Place, publisher, year, edition, pages
2013. Vol. 579, 31-33 p.
Keyword [en]
Metal hydrides, Transition metal alloys and compounds, Chemical synthesis, Crystal structure
National Category
Materials Engineering Materials Chemistry
Identifiers
URN: urn:nbn:se:su:diva-95411DOI: 10.1016/j.jallcom.2013.05.024ISI: 000324523500006OAI: oai:DiVA.org:su-95411DiVA: diva2:660958
Note

AuthorCount:3;

Available from: 2013-10-31 Created: 2013-10-28 Last updated: 2017-12-06Bibliographically approved

Open Access in DiVA

No full text

Other links

Publisher's full text

Search in DiVA

By author/editor
Fahlquist, HenrikKadir, KarimNoréus, Dag
By organisation
Department of Materials and Environmental Chemistry (MMK)
In the same journal
Journal of Alloys and Compounds
Materials EngineeringMaterials Chemistry

Search outside of DiVA

GoogleGoogle Scholar

doi
urn-nbn

Altmetric score

doi
urn-nbn
Total: 148 hits
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf