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Self-Assembly Mechanism of Folate-Templated Mesoporous Silica
Stockholm University, Faculty of Science, Department of Materials and Environmental Chemistry (MMK), Materials Chemistry.
Stockholm University, Faculty of Science, Department of Materials and Environmental Chemistry (MMK).
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2013 (English)In: Langmuir, ISSN 0743-7463, E-ISSN 1520-5827, Vol. 29, no 38, 12003-12012 p.Article in journal (Refereed) Published
Abstract [en]

A method to form ordered mesoporous silica based on the use of folate supramolecular templates has been developed. Evidence based on in situ small-angle X-ray scattering (SAXS), electron microscopy, infrared spectroscopy, and in situ conductivity measurements are used to investigate the organic inorganic interactions and synthesis mechanism. The behavior of folate molecules in solution differs distinctively from that of surfactants commonly used for the preparation of ordered mesoporous silica phases, notably with the absence of a critical micellar concentration. In situ SAXS studies reveal fluctuations in X-ray scattering intensities consistent with the condensation of the silica precursor surrounding the folate template and the growth of the silica mesostructure in the initial stages. High-angle X-ray diffraction shows that the folate template is well-ordered within the pores even after a few minutes of synthesis. Direct structural data for the self-assembly of folates into chiral tetramers within the pores of mesoporous silica provide evidence for the in register stacking of folate tetramers, resulting in a chiral surface of rotated tetramers, with a rotation angle of 30 degrees. Additionally, the self-assembled folates within pores were capable of adsorbing a considerable amount of CO2 gas through the cavity space of the tetramers. The study demonstrates the validity of using a naturally occurring template to produce relevant and functional mesoporous materials.

Place, publisher, year, edition, pages
American Chemical Society (ACS), 2013. Vol. 29, no 38, 12003-12012 p.
National Category
Chemical Sciences Materials Chemistry
URN: urn:nbn:se:su:diva-101024DOI: 10.1021/la401532jISI: 000330148500022OAI: diva2:699413


Funding agencies:

Swedish Research Council 2009-4716; Swedish Energy Agency;  Spanish Ministry of Sport and Education JC2009-00141 

Available from: 2014-02-27 Created: 2014-02-21 Last updated: 2014-02-27Bibliographically approved

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Bacsik, ZoltanHedin, NiklasGarcia-Bennett, Alfonso E.
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Materials ChemistryDepartment of Materials and Environmental Chemistry (MMK)Inorganic and Structural Chemistry
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