Efficient Palladium-Catalyzed Aminocarbonylation of Aryl Iodides Using Palladium Nanoparticles Dispersed on Siliceous Mesocellular Foam
2014 (English)In: Chemistry - A European Journal, ISSN 0947-6539, E-ISSN 1521-3765, Vol. 20, no 20, 5885-5889 p.Article in journal (Refereed) Published
A highly dispersed nanopalladium catalyst supported on mesocellular foam (MCF), was successfully used in the heterogeneous catalysis of aminocarbonylation reactions. During the preliminary evaluation of this catalyst it was discovered that the supported palladium nanoparticles exhibited a “release and catch” effect, meaning that a minor amount of the heterogeneous palladium became soluble and catalyzed the reaction, after which it re-deposited onto the support.
Place, publisher, year, edition, pages
Weinheim: Wiley-VCH Verlag GmbH & Co. KGaA , 2014. Vol. 20, no 20, 5885-5889 p.
amides, aminocarbonylation, heterogeneous catalysis, palladium, release and catch
Research subject Organic Chemistry
IdentifiersURN: urn:nbn:se:su:diva-102132DOI: 10.1002/chem.201402029ISI: 000335433500004OAI: oai:DiVA.org:su-102132DiVA: diva2:708221
FunderEU, European Research Council, 247014Swedish Research CouncilKnut and Alice Wallenberg FoundationBerzelii Centre EXSELENT