Change search
ReferencesLink to record
Permanent link

Direct link
A novel 3D metal-organic framework with silver iodide anion cluster [Ag14I16](2-) as node: Synthesis, structure, and fluorescence property
Stockholm University, Faculty of Science, Department of Materials and Environmental Chemistry (MMK).
Show others and affiliations
2014 (English)In: Inorganic Chemistry Communications, ISSN 1387-7003, E-ISSN 1879-0259, Vol. 40, 220-222 p.Article in journal (Refereed) Published
Abstract [en]

A novel 3D silver iodide metal-organic framework {[Ag14I16(HDABCO)(2)]center dot(DABCO)}(n) (DABCO = 1,4-diazabicyclo[2.2.2]octane) (1) has been synthesized solvothermally. In this compound, a [Ag14I16](2-) anion cluster was formed by twelve AgI4 tetrahedra and two AgI3 triangles by sharing their edges, in which its charge is compensated by two mono-protoned HDABCO(+). Each [Ag14I16](2-) cluster connects to six neighboring clusters by sharing corner I- ions between the AgI4 tetrahedra, resulting in a 3D framework. The compound 1 displays intense fluorescence emission with maximum at 400 nm and 465 nm upon 310 nm excitation at room temperature.

Place, publisher, year, edition, pages
2014. Vol. 40, 220-222 p.
Keyword [en]
Coordination polymer, Silver iodide anion cluster, Crystal structure, Fluorescence property, Thermal stability
National Category
Inorganic Chemistry
URN: urn:nbn:se:su:diva-102082DOI: 10.1016/j.inoche.2013.12.016ISI: 000331506600051OAI: diva2:708416


Available from: 2014-03-27 Created: 2014-03-26 Last updated: 2014-03-27Bibliographically approved

Open Access in DiVA

No full text

Other links

Publisher's full text
By organisation
Department of Materials and Environmental Chemistry (MMK)
In the same journal
Inorganic Chemistry Communications
Inorganic Chemistry

Search outside of DiVA

GoogleGoogle Scholar
The number of downloads is the sum of all downloads of full texts. It may include eg previous versions that are now no longer available

Altmetric score

Total: 53 hits
ReferencesLink to record
Permanent link

Direct link