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Combined Heterogeneous Metal/Chiral Amine: Multiple Relay Catalysis for Versatile Eco-Friendly Synthesis
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
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2014 (English)In: Angewandte Chemie International Edition, ISSN 1433-7851, E-ISSN 1521-3773, Vol. 53, no 13, 3447-3451 p.Article in journal (Refereed) Published
Abstract [en]

Herein is described a versatile and broad synergistic strategy for expansion of chemical space and the synthesis of valuable molecules (e.g. carbocycles and heterocycles), with up to three quaternary stereocenters, in a highly enantioselective fashion from simple alcohols (31examples, 95:5 to >99.5:0.5 e.r.) using integrated heterogeneous metal/chiral amine multiple relay catalysis and air/O-2 as the terminal oxidant. A novel highly 1,4-selective heterogeneous metal/amine co-catalyzed hydrogenation of enals was also added to the relay catalysis sequences.

Place, publisher, year, edition, pages
2014. Vol. 53, no 13, 3447-3451 p.
Keyword [en]
alcohols, heterogeneous catalysis, homogeneous catalysis, hydrogenation, oxidation
National Category
Chemical Sciences
Identifiers
URN: urn:nbn:se:su:diva-102952DOI: 10.1002/anie.201310216ISI: 000333001500028OAI: oai:DiVA.org:su-102952DiVA: diva2:715019
Funder
Swedish Research CouncilVINNOVAKnut and Alice Wallenberg Foundation
Note

AuthorCount:9;

Available from: 2014-04-30 Created: 2014-04-25 Last updated: 2017-12-05Bibliographically approved

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