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Access to Cinnamyl Derivatives from Arenes and Allyl Esters by a Biomimetic Aerobic Oxidative Dehydrogenative Coupling
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
2014 (English)In: Organic Letters, ISSN 1523-7060, E-ISSN 1523-7052, Vol. 16, no 6, 1664-1667 p.Article in journal (Refereed) Published
Abstract [en]

An efficient biomimetic aerobic oxidative dehydrogenative alkenylation of arenes with allyl esters is presented. The reaction proceeds under an ambient pressure of oxygen with relatively low catalyst loading of palladium acetate, employing catalytic amounts of electron-transfer mediators (ETMs). This study represents a new environmentally friendly method for the synthesis of cinnamyl derivatives.

Place, publisher, year, edition, pages
2014. Vol. 16, no 6, 1664-1667 p.
National Category
Organic Chemistry
URN: urn:nbn:se:su:diva-103297DOI: 10.1021/ol500326gISI: 000333477400033OAI: diva2:717692
EU, European Research Council, 247014Swedish Research CouncilKnut and Alice Wallenberg Foundation


Available from: 2014-05-16 Created: 2014-05-12 Last updated: 2016-04-14Bibliographically approved

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Gigant, NicolasBäckvall, Jan-Erling
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