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Palladium-Catalyzed Alkoxycarbonylation of Terminal Alkenes To Produce alpha, beta-Unsaturated Esters: The Key Role of Acetonitrile as a Ligand
Stockholm University, Faculty of Science, Department of Organic Chemistry.
2014 (English)In: Chemistry - A European Journal, ISSN 0947-6539, E-ISSN 1521-3765, Vol. 20, no 16, 4542-4547 p.Article in journal (Refereed) Published
Abstract [en]

A mild protocol has been developed for the Pd-II-catalyzed alkoxycarbonylation of terminal olefins to produce ,-unsaturated esters with a wide range of substrates. Key features are the use of MeCN as solvent (and/or ligand) to control the reactivity of the intermediate Pd complexes and the combination of CO with O-2, which facilitates the Cu-II-mediated reoxidation of the Pd-0 complex to Pd-II and prevents double carbonylation.

Place, publisher, year, edition, pages
2014. Vol. 20, no 16, 4542-4547 p.
Keyword [en]
carbonylation, homogeneous catalysis, oxygen, palladium, solvent effects
National Category
Chemical Sciences
URN: urn:nbn:se:su:diva-103952DOI: 10.1002/chem.201304798ISI: 000334080800005OAI: diva2:722887


Available from: 2014-06-09 Created: 2014-05-27 Last updated: 2015-10-01Bibliographically approved

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Kocovsky, Pavel
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