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Palladium-Catalyzed Stereoselective Intramolecular Oxidative Amidation of Alkenes in the Synthesis of 1,3-and 1,4-Amino Alcohols and 1,3-Diamines
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2014 (English)In: Chemistry - A European Journal, ISSN 0947-6539, E-ISSN 1521-3765, Vol. 20, no 17, 4901-4905 p.Article in journal (Refereed) Published
Abstract [en]

An efficient and practical Pd-catalyzed intramolecular oxidative allylic amidation provides facile access to derivatives of 1,3- and 1,4-amino alcohols and 1,3-diamines. The method operates under mild reaction conditions (RT) with molecular oxygen (1atm) as the sole reoxidant of Pd. Excellent diastereoselectivities were attained with substrates bearing a secondary stereogenic center

Place, publisher, year, edition, pages
2014. Vol. 20, no 17, 4901-4905 p.
Keyword [en]
allylic compounds, amination, cyclization, homogeneous catalysis, palladium
National Category
Organic Chemistry
Identifiers
URN: urn:nbn:se:su:diva-105149DOI: 10.1002/chem.201400123ISI: 000334396900007OAI: oai:DiVA.org:su-105149DiVA: diva2:727976
Funder
Wenner-Gren Foundations
Note

AuthorCount:5;

Available from: 2014-06-23 Created: 2014-06-23 Last updated: 2017-12-05Bibliographically approved

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Kocovsky, Pavel
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