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Synthesis, Crystal Structure and Thermal Decomposition of the New Cadmium Selenite Chloride, Cd-4(SeO3)(2)OCl2
Stockholm University, Faculty of Science, Department of Materials and Environmental Chemistry (MMK).
Stockholm University, Faculty of Science, Department of Materials and Environmental Chemistry (MMK).
2014 (English)In: PLoS ONE, ISSN 1932-6203, E-ISSN 1932-6203, Vol. 9, no 5, e97175- p.Article in journal (Refereed) Published
Abstract [en]

A synthetic study in the Cd-Se-O-Cl system led to formation of the new oxochloride compound Cd-4(SeO3)(2)OCl2 via solid state reactions. The compound crystallizes in the orthorhombic space group Fmmm with cell parameters a = 7.3610(3) angstrom, b = 15.4936(2) angstrom, c = 17.5603(3) angstrom, Z = 8, S = 0.969, F(000) = 2800, R = 0.0185, R-w = 0.0384. Single crystal X-ray data were collected at 293 K. The crystal structure can be considered as layered and the building units are distorted [Cd(1)O-6] octahedra, distorted [Cd(2)O-8] cubes, irregular [Cd(3)O4Cl2] polyhedra and SeO3E trigonal pyramids. There are two crystallographically unique Cl atoms that both are half occupied. Thermogravimetric studies show that the compound starts to decompose at 500 degrees C. The crystal structure of the new compound is closely related to the previously described compound Cd-4(SeO3)(2)Cl-4(H2O).

Place, publisher, year, edition, pages
2014. Vol. 9, no 5, e97175- p.
National Category
Inorganic Chemistry
Research subject
Inorganic Chemistry
Identifiers
URN: urn:nbn:se:su:diva-107051DOI: 10.1371/journal.pone.0097175ISI: 000339563400015OAI: oai:DiVA.org:su-107051DiVA: diva2:742806
Note

AuthorCount:4;

Available from: 2014-09-02 Created: 2014-09-02 Last updated: 2017-12-05Bibliographically approved

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