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Palladium-Catalyzed Oxidative Domino Carbocyclization- Carbonylation-Alkynylation of Enallenes
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
2014 (English)In: Organic Letters, ISSN 1523-7060, E-ISSN 1523-7052, Vol. 16, no 16, 4174-4177 p.Article in journal (Refereed) Published
Abstract [en]

An oxidative carbocyclization-carbonylation-alkynylation reaction cascade has been developed using catalytic amounts of palladium(II) salts. The domino reaction proceeds efficiently, giving the corresponding ynones in good to excellent yields under operationally simple conditions. A wide range of aromatic and aliphatic terminal alkynes with various functional groups are tolerated under the reaction conditions.

Place, publisher, year, edition, pages
2014. Vol. 16, no 16, 4174-4177 p.
National Category
Organic Chemistry
URN: urn:nbn:se:su:diva-107579DOI: 10.1021/ol501862zISI: 000340517200030OAI: diva2:748657
EU, European Research CouncilSwedish Research CouncilBerzelii Centre EXSELENTWenner-Gren Foundations


Available from: 2014-09-21 Created: 2014-09-20 Last updated: 2016-04-26Bibliographically approved

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Volla, Chandra M. R.Bäckvall, Jan-Erling
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