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Transition metal-catalyzed redox isomerization of codeine and morphine in water
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
2014 (English)In: RSC Advances, ISSN 2046-2069, E-ISSN 2046-2069, Vol. 4, no 74, 39519-39522 p.Article in journal (Refereed) Published
Abstract [en]

A water-soluble rhodium complex formed from commercially available [Rh(COD)(CH3CN)(2)]BF4 and 1,3,5-triaza-7-phosphaadamantane (PTA) catalyzes the isomerization of both codeine and morphine into hydrocodone and hydromorphone with very high efficiency. The reaction is performed in water, allowing isolation of the final products by simple filtration, which results in very high isolated yields. The reactions can be easily scaled up to 100 g.

Place, publisher, year, edition, pages
Royal Society of Chemistry, 2014. Vol. 4, no 74, 39519-39522 p.
National Category
Organic Chemistry
Research subject
Organic Chemistry
Identifiers
URN: urn:nbn:se:su:diva-108400DOI: 10.1039/c4ra07735kISI: 000341778500047OAI: oai:DiVA.org:su-108400DiVA: diva2:757522
Funder
VINNOVASwedish Research CouncilKnut and Alice Wallenberg FoundationBerzelii Centre EXSELENT
Note

AuthorCount:4;

Available from: 2014-10-22 Created: 2014-10-22 Last updated: 2017-12-05Bibliographically approved

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Bermejo Gómez, AntonioBäckvall, Jan-ErlingMartin-Matute, Belén
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