A Series of Highly Stable Mesoporous Metalloporphyrin Fe-MOFs
2014 (English)In: Journal of the American Chemical Society, ISSN 0002-7863, E-ISSN 1520-5126, Vol. 136, no 40, 13983-13986 p.Article in journal (Refereed) Published
A series of mesoporous metalloporphyrin Fe-MOFs, namely PCN-600(M) (M = Mn, Fe, Co, Ni, Cu), have been synthesized using the preassembled [Fe3O(OOCCH3)(6)] building block. PCN-600 exhibits a one-dimensional channel as large as 3.1 nm and the highest experimental pore volume of 1.80 cm(3) g(-1) among all the reported porphyrinic MOFs. It also shows very high stability in aqueous solutions with pH values ranging from 2-11 and is to our knowledge the only mesoporous porphyrinic MOF stable under basic aqueous conditions. PCN-600(Fe) has been demonstrated as an effective peroxidase mimic to catalyze the co-oxidation reaction.
Place, publisher, year, edition, pages
2014. Vol. 136, no 40, 13983-13986 p.
IdentifiersURN: urn:nbn:se:su:diva-109271DOI: 10.1021/ja507269nISI: 000343026700008OAI: oai:DiVA.org:su-109271DiVA: diva2:764871