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Enantioselective α-arylation of cyclohexanones with diaryl iodonium salts: Application to the synthesis of (-)-epibatidine.
Bristol University.
Stockholm University, Faculty of Science, Department of Organic Chemistry. University of Bristol, Bristol, UK.
2005 (English)In: Angewandte Chemie International Edition, ISSN 1433-7851, E-ISSN 1521-3773, Vol. 44, no 34, 5516-5519 p.Article in journal (Refereed) Published
Abstract [en]

The direct asym. α-arylation of prochiral ketones has been effected using chiral lithium amide bases and diaryl iodonium salts. The methodol. has been employed in a short total synthesis of the alkaloid (-)-epibatidine. [on SciFinder(R)]

Place, publisher, year, edition, pages
2005. Vol. 44, no 34, 5516-5519 p.
Keyword [en]
epibatidine synthesis enantioselective arylation, cyclohexanone diaryl iodonium enantioselective alpha arylation
National Category
Organic Chemistry
Research subject
Organic Chemistry
Identifiers
URN: urn:nbn:se:su:diva-109684DOI: 10.1002/anie.200501745ISI: 000231639400025OAI: oai:DiVA.org:su-109684DiVA: diva2:766465
Funder
Swedish Research Council
Note

CAPLUS AN 2005:999741(Journal)

Available from: 2014-11-27 Created: 2014-11-27 Last updated: 2017-12-05Bibliographically approved

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