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Tandem alpha-Alkylation/Asymmetric Transfer Hydrogenation of Acetophenones with Primary Alcohols
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
2014 (English)In: European Journal of Organic Chemistry, ISSN 1434-193X, E-ISSN 1099-0690, no 30, 6639-6642 p.Article in journal (Refereed) Published
Abstract [en]

A tandem -alkylation/asymmetric transfer hydrogenation of acetophenones with primary alcohols, mediated by a single ruthenium catalyst, is described. Under optimized reaction conditions and with use of [Ru(p-cymene)Cl-2](2) in combination with an amino acid hydroxyamide ligand, the chiral secondary alcohol products were isolated in moderate yields and in moderate to good enantiomeric excess (up to 89% ee).

Place, publisher, year, edition, pages
2014. no 30, 6639-6642 p.
Keyword [en]
Alkylation, Amino acids, Asymmetric catalysis, Reduction, Ruthenium
National Category
Organic Chemistry
Identifiers
URN: urn:nbn:se:su:diva-109980DOI: 10.1002/ejoc.201403032ISI: 000343872900007OAI: oai:DiVA.org:su-109980DiVA: diva2:768398
Funder
Knut and Alice Wallenberg FoundationSwedish Research Council
Note

AuthorCount:4;

Available from: 2014-12-03 Created: 2014-12-02 Last updated: 2017-12-05Bibliographically approved

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Lundberg, HelenaAdolfsson, Hans
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