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Ruthenium-Catalyzed Tandem-Isomerization/Asymmetric Transfer Hydrogenation of Allylic Alcohols
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
2014 (English)In: Chemistry - A European Journal, ISSN 0947-6539, E-ISSN 1521-3765, Vol. 20, no 49, 16102-16106 p.Article in journal (Refereed) Published
Abstract [en]

A one-pot procedure for the direct conversion of racemic allylic alcohols to enantiomerically enriched saturated alcohols is presented. The tandem-isomerization/asymmetric transfer hydrogenation process is efficiently catalyzed by [{Ru(p-cymene)Cl-2}(2)] in combination with the -amino acid hydroxyamide ligand 1, and performed under mild conditions in a mixture of ethanol and THF. The saturated alcohol products are isolated in good to excellent chemical yields and in enantiomeric excess up to 93%.

Place, publisher, year, edition, pages
2014. Vol. 20, no 49, 16102-16106 p.
Keyword [en]
allylic alcohols, asymmetric catalysis, isomerization, reduction, ruthenium
National Category
Organic Chemistry
Identifiers
URN: urn:nbn:se:su:diva-111419DOI: 10.1002/chem.201405207ISI: 000345515700012OAI: oai:DiVA.org:su-111419DiVA: diva2:775744
Funder
Swedish Research CouncilKnut and Alice Wallenberg Foundation
Note

AuthorCount:3;

Available from: 2015-01-05 Created: 2015-01-02 Last updated: 2017-12-05Bibliographically approved

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Slagbrand, ToveLundberg, HelenaAdolfsson, Hans
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