A Highly Stable Zeotype Mesoporous Zirconium Metal-Organic Framework with Ultralarge Pores
2015 (English)In: Angewandte Chemie International Edition, ISSN 1433-7851, E-ISSN 1521-3773, Vol. 54, no 1, 149-154 p.Article in journal (Refereed) Published
Through topological rationalization, a zeotype mesoporous Zr-containing metal-organic framework (MOF), namely PCN-777, has been designed and synthesized. PCN-777 exhibits the largest cage size of 3.8nm and the highest pore volume of 2.8cm(3)g(-1) among reported Zr-MOFs. Moreover, PCN-777 shows excellent stability in aqueous environments, which makes it an ideal candidate as a support to incorporate different functional moieties. Through facile internal surface modification, the interaction between PCN-777 and different guests can be varied to realize efficient immobilization.
Place, publisher, year, edition, pages
2015. Vol. 54, no 1, 149-154 p.
carboxylate ligands, host-guest systems, mesoporous materials, metal-organic frameworks, zirconium
IdentifiersURN: urn:nbn:se:su:diva-113543DOI: 10.1002/anie.201409334ISI: 000347065100017OAI: oai:DiVA.org:su-113543DiVA: diva2:787082