The First One-Pot Synthesis of Metal-Organic Frameworks Functionalised with Two Transition-Metal Complexes
2015 (English)In: Chemistry - A European Journal, ISSN 0947-6539, E-ISSN 1521-3765, Vol. 21, no 2, 861-866 p.Article in journal (Refereed) Published
The synthesis of a metal-organic framework (UiO-67) functionalised simultaneously with two different transition metal complexes (Ir and Pd or Rh) through a one-pot procedure is reported for the first time. This has been achieved by an iterative modification of the synthesis parameters combined with characterisation of the resulting materials using different techniques, including X-ray absorption spectroscopy (XAS). The method also allows the first synthesis of UiO-67 with a very wide range of loadings (from 4 to 43 mol%) of an iridium complex ([IrCp*(bpydc)(Cl)Cl](2-); bpydc=2,2'-bipyridine-5,5'-dicarboxylate, Cp* = pentamethylcyclopentadienyl) through a pre-functionalisation methodology.
Place, publisher, year, edition, pages
2015. Vol. 21, no 2, 861-866 p.
functionalisation, metal-organic frameworks, microporous materials, synthesis design, transition metal complexes
IdentifiersURN: urn:nbn:se:su:diva-113542DOI: 10.1002/chem.201403909ISI: 000347231300042OAI: oai:DiVA.org:su-113542DiVA: diva2:787088