Change search
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf
Carbonate-Based Zeolitic Imidazolate Framework for Highly Selective CO2 Capture
Stockholm University, Faculty of Science, Department of Materials and Environmental Chemistry (MMK).
Stockholm University, Faculty of Science, Department of Materials and Environmental Chemistry (MMK).
2015 (English)In: Inorganic Chemistry, ISSN 0020-1669, E-ISSN 1520-510X, Vol. 54, no 4, 1816-1821 p.Article in journal (Refereed) Published
Abstract [en]

In this study, we report the formation of a new crystal structure, ZIF-CO3-1, which results from the reaction of Zn2+, 2-methylimidazole, and carbonate. ZIF-CO3-1 can be synthesized solvothermally in N,N-dimethylformamide (DMF)/water (H2O) or by utilizing of CO2 gas at various temperatures in DMF/H2O or H2O. This reaction selectively consumes CO2 because CO2 is incorporated in the ZIF as carbonate. CO2 can be quantitatively released by acidifying the ZIF. Powder X-ray diffraction, single-crystal X-ray diffraction, FTIR spectroscopy, scanning electron microscopy, elemental analysis, and thermogravimetric analysis were used to characterize the ZIF structure. ZIF-CO3-1 (chemical formula C9H(10)N4O(3)Zn(2)), crystallizes in the orthorhombic crystal system with noncentrosymmetric space group Pba2.

Place, publisher, year, edition, pages
2015. Vol. 54, no 4, 1816-1821 p.
National Category
Chemical Sciences
Identifiers
URN: urn:nbn:se:su:diva-115680DOI: 10.1021/ic5027174ISI: 000349656600074PubMedID: 25650775OAI: oai:DiVA.org:su-115680DiVA: diva2:799696
Note

AuthorCount:4;

Available from: 2015-03-31 Created: 2015-03-27 Last updated: 2017-12-04Bibliographically approved

Open Access in DiVA

No full text

Other links

Publisher's full textPubMed

Search in DiVA

By author/editor
Su, JieZou, Xiaodong
By organisation
Department of Materials and Environmental Chemistry (MMK)
In the same journal
Inorganic Chemistry
Chemical Sciences

Search outside of DiVA

GoogleGoogle Scholar

doi
pubmed
urn-nbn

Altmetric score

doi
pubmed
urn-nbn
Total: 110 hits
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf