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Direct Allylation of Quinones with Allylboronates
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
2015 (English)In: Journal of Organic Chemistry, ISSN 0022-3263, E-ISSN 1520-6904, Vol. 80, no 6, 3343-3348 p.Article in journal (Refereed) Published
Abstract [en]

Allylboronates undergo C-H allylation of unsubstituted or monosubstituted benzoquinone and naphthoquinone substrates. In the case of 2,5- or 2,6-disubstituted quinones addition involving the substituted carbon takes place. Allylation with stereodefined allylboronates occurs with retention of the configuration.

Place, publisher, year, edition, pages
American Chemical Society (ACS), 2015. Vol. 80, no 6, 3343-3348 p.
National Category
Organic Chemistry
Identifiers
URN: urn:nbn:se:su:diva-116999DOI: 10.1021/acs.joc.5b00264ISI: 000351558400045PubMedID: 25728494OAI: oai:DiVA.org:su-116999DiVA: diva2:811892
Funder
Swedish Research CouncilKnut and Alice Wallenberg Foundation
Note

AuthorCount:3;

Available from: 2015-05-13 Created: 2015-05-05 Last updated: 2017-12-04Bibliographically approved

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