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Electrocatalytic Water Oxidation by a Dinuclear Copper Complex in a Neutral Aqueous Solution
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2015 (English)In: Angewandte Chemie International Edition, ISSN 1433-7851, E-ISSN 1521-3773, Vol. 54, no 16, 4909-4914 p.Article in journal (Refereed) Published
Abstract [en]

Electrocatalytic water oxidation using the oxidatively robust 2,7-[bis(2-pyridylmethyl)aminomethyl]-1,8-naphthyridine ligand (BPMAN)-based dinuclear copper(II) complex, [Cu-2(BPMAN)(-OH)](3+), has been investigated. This catalyst exhibits high reactivity and stability towards water oxidation in neutral aqueous solutions. DFT calculations suggest that the OO bond formation takes place by an intramolecular direct coupling mechanism rather than by a nucleophilic attack of water on the high-oxidation-state (CuO)-O-IV moiety.

Place, publisher, year, edition, pages
2015. Vol. 54, no 16, 4909-4914 p.
Keyword [en]
copper, homogeneous catalysis, OO coupling, superoxide complexes, water oxidation
National Category
Organic Chemistry
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URN: urn:nbn:se:su:diva-117455DOI: 10.1002/anie.201411625ISI: 000352622400041PubMedID: 25678035OAI: oai:DiVA.org:su-117455DiVA: diva2:812540
Note

AuthorCount:7;

Available from: 2015-05-19 Created: 2015-05-19 Last updated: 2017-12-04Bibliographically approved

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Siegbahn, Per E. M.
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