Palladium(II)/Bronsted Acid-Catalyzed Enantioselective Oxidative Carbocyclization-Borylation of Enallenes
Number of Authors: 5
2015 (English)In: Angewandte Chemie International Edition, ISSN 1433-7851, E-ISSN 1521-3773, Vol. 54, no 20, 6024-6027 p.Article in journal (Refereed) Published
An enantioselective oxidative carbocyclization-borylation of enallenes that is catalyzed by palladium(II) and a Bronsted acid was developed. Biphenol-type chiral phosphoric acids were superior co-catalysts for inducing the enantioselective cyclization. A number of chiral borylated carbocycles were synthesized in high enantiomeric excess.
Place, publisher, year, edition, pages
2015. Vol. 54, no 20, 6024-6027 p.
carbocyclization, chiral anion, chiral phosphoric acid, oxidation, palladium
IdentifiersURN: urn:nbn:se:su:diva-117774DOI: 10.1002/anie.201501048ISI: 000354255400041OAI: oai:DiVA.org:su-117774DiVA: diva2:817616