Change search
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf
Vinylic MIDA Boronates: New Building Blocks for the Synthesis of Aza-Heterocycles
Show others and affiliations
Number of Authors: 10
2015 (English)In: Chemistry - A European Journal, ISSN 0947-6539, E-ISSN 1521-3765, Vol. 21, no 20, 7394-7398 p.Article in journal (Refereed) Published
Abstract [en]

A two-step synthesis of structurally diverse pyrrole-containing bicyclic systems is reported. ortho-Nitro-haloarenes coupled with vinylic N-methyliminodiacetic acid (MIDA) boronates generate ortho-vinyl-nitroarenes, which undergo a metal-free nitrene insertion, resulting in a new pyrrole ring. This novel synthetic approach has a wide substrate tolerance and it is applicable in the preparation of more complex drug-like molecules. Interestingly, an ortho-nitro-allylarene derivative furnished a cyclic beta-aminophosphonate motif.

Place, publisher, year, edition, pages
2015. Vol. 21, no 20, 7394-7398 p.
Keyword [en]
aminophosphonate, boronate, cyclization, heterocycles, MIDA, nitrene
National Category
Chemical Sciences
Identifiers
URN: urn:nbn:se:su:diva-118363DOI: 10.1002/chem.201406549ISI: 000354027300015OAI: oai:DiVA.org:su-118363DiVA: diva2:822196
Available from: 2015-06-16 Created: 2015-06-15 Last updated: 2017-12-04Bibliographically approved

Open Access in DiVA

No full text

Other links

Publisher's full text

Search in DiVA

By author/editor
Eriksson, LarsStenmark, Pål
By organisation
Department of Materials and Environmental Chemistry (MMK)Department of Biochemistry and Biophysics
In the same journal
Chemistry - A European Journal
Chemical Sciences

Search outside of DiVA

GoogleGoogle Scholar

doi
urn-nbn

Altmetric score

doi
urn-nbn
Total: 71 hits
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf