Change search
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf
Recycled Poly(vinyl alcohol) Sponge for Carbon Encapsulation of Size-Tunable Tin Dioxide Nanocrystalline Composites
Stockholm University, Faculty of Science, Department of Materials and Environmental Chemistry (MMK).
Number of Authors: 4
2015 (English)In: ChemSusChem, ISSN 1864-5631, E-ISSN 1864-564X, Vol. 8, no 12, 2084-2092 p.Article in journal (Refereed) Published
Abstract [en]

The recycling of industrial materials could reduce their environmental impact and waste haulage fees and result in sustainable manufacturing. In this work, commercial poly(vinyl alcohol) (PVA) sponges are recycled into a macroporous carbon matrix to encapsulate size-tunable SnO2 nanocrystals as anode materials for lithium-ion batteries (LIBs) through a scalable, flash-combustion method. The hydroxyl groups present copiously in the recycled PVA sponges guarantee a uniform chemical coupling with a tin(IV) citrate complex through intermolecular hydrogen bonds. Then, a scalable, ultrafast combustion process (30s) carbonizes the PVA sponge into a 3D carbon matrix. This PVA-sponge-derived carbon could not only buffer the volume fluctuations upon the Li-Sn alloying and dealloying processes but also afford a mixed conductive network, that is, a continuous carbon framework for electrical transport and macropores for facile electrolyte percolation. The best-performing electrode based on this composite delivers a rate performance up to 9.72C (4Ag(-1)) and long-term cyclability (500cycles) for Li+ ion storage. Moreover, cyclic voltammograms demonstrate the coexistence of alloying and dealloying processes and non-diffusion-controlled pseudocapacitive behavior, which collectively contribute to the high-rate Li+ ion storage.

Place, publisher, year, edition, pages
2015. Vol. 8, no 12, 2084-2092 p.
Keyword [en]
carbon, energy storage, flash combustion, lithium, polymers
National Category
Chemical Sciences
Identifiers
URN: urn:nbn:se:su:diva-118941DOI: 10.1002/cssc.201500297ISI: 000356725300010OAI: oai:DiVA.org:su-118941DiVA: diva2:842981
Available from: 2015-07-24 Created: 2015-07-21 Last updated: 2017-12-04Bibliographically approved

Open Access in DiVA

No full text

Other links

Publisher's full text

Search in DiVA

By author/editor
Tai, Cheuk-Wai
By organisation
Department of Materials and Environmental Chemistry (MMK)
In the same journal
ChemSusChem
Chemical Sciences

Search outside of DiVA

GoogleGoogle Scholar

doi
urn-nbn

Altmetric score

doi
urn-nbn
Total: 39 hits
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf