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Artificial Metalloenzymes in Asymmetric Catalysis: Key Developments and Future Directions
Stockholm University, Faculty of Science, Department of Organic Chemistry.
2015 (English)In: Advanced Synthesis and Catalysis, ISSN 1615-4150, E-ISSN 1615-4169, Vol. 357, no 8, 1567-1586 p.Article in journal (Refereed) Published
Abstract [en]

Artificial metalloenzymes combine the excellent selective recognition/binding properties of enzymes with transition metal catalysts, and therefore many asymmetric transformations can benefit from these entities. The search for new successful strategies in the construction of metal-enzyme hybrid catalysts has therefore become a very active area of research. This review discusses all the developed strategies and the latest advances in the synthesis and application in asymmetric catalysis of artificial metalloenzymes with future directions for their design, synthesis and application (Sections 2-4). Finally, advice is presented (to the non-specialist) on how to prepare and use artificial metalloenzymes (Section 5).

Place, publisher, year, edition, pages
WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim , 2015. Vol. 357, no 8, 1567-1586 p.
Keyword [en]
artificial metalloenzymes, asymmetric catalysis, hybrid catalysts
National Category
Chemical Sciences
URN: urn:nbn:se:su:diva-118535DOI: 10.1002/adsc.201500290ISI: 000355235700002OAI: diva2:846596
Swedish Research CouncilBerzelii Centre EXSELENTKnut and Alice Wallenberg Foundation
Available from: 2015-08-17 Created: 2015-06-22 Last updated: 2016-10-12Bibliographically approved

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Bäckvall, Jan-E.
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