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Catalytic Intramolecular Aminofluorination, Oxyfluorination, and Carbofluorination with a Stable and Versatile Hypervalent Fluoroiodine Reagent
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Number of Authors: 2
2015 (English)In: Angewandte Chemie International Edition, ISSN 1433-7851, E-ISSN 1521-3773, Vol. 54, no 29, 8533-8537 p.Article in journal (Refereed) Published
Abstract [en]

Application of a fluoroiodine analogue of the Togni reagent was studied in fluorocyclization reactions. In the presence of a transition-metal catalyst the applied fluoroiodine reagent can be used for aminofluorination, oxyfluorination, and carbofluorination reactions. The described procedure has a very broad synthetic scope for preparation of functionalized hetero- and isocyclic compounds having a tertiary fluorine substituent.

Place, publisher, year, edition, pages
2015. Vol. 54, no 29, 8533-8537 p.
Keyword [en]
copper, cyclizations, fluorine, heterocycles, homogeneous catalysis
National Category
Organic Chemistry
Identifiers
URN: urn:nbn:se:su:diva-119552DOI: 10.1002/anie.201503373ISI: 000358050300042OAI: oai:DiVA.org:su-119552DiVA: diva2:846850
Available from: 2015-08-18 Created: 2015-08-17 Last updated: 2017-12-04Bibliographically approved

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