Olefin-Directed Palladium-Catalyzed Regio- and Stereoselective Oxidative Arylation of Allenes
Number of Authors: 4
2015 (English)In: Angewandte Chemie International Edition, ISSN 1433-7851, E-ISSN 1521-3773, Vol. 54, no 31, 9066-9069 p.Article in journal (Refereed) Published
An olefin-directed palladium-catalyzed oxidative regio- and stereoselective arylation of allenes to afford 1,3,6-trienes has been established. A number of functionalized allenes, including 2,3- and 3,4-dienoates and 3,4-dienol derivatives, have been investigated and found to undergo the olefin-directed allene arylation. The olefin moiety has been proven to be a crucial element for the arylating transformation.
Place, publisher, year, edition, pages
2015. Vol. 54, no 31, 9066-9069 p.
allenes, arylation, directing groups, oxidation, palladium
IdentifiersURN: urn:nbn:se:su:diva-120087DOI: 10.1002/anie.201502924ISI: 000358501500035OAI: oai:DiVA.org:su-120087DiVA: diva2:851657