Highly Enantioselective Asymmetric Isomerization of Primary AllylicAlcohols with an Iridium–N,P Complex
2011 (English)In: Chemistry - A European Journal, ISSN 0947-6539, E-ISSN 1521-3765, Vol. 17, 11143-11145 p.Article in journal (Refereed) Published
Highly enantioselective asym. isomerization of a range of E- and Z- trisubstituted primary allylic alcs. to the corresponding chiral aldehydes catalyzed by a N,P-ligated iridium complex is reported. Notably, the selectivity of this catalyst was less sensitive to steric effects in the asym. isomerization of Z-trisubstituted allylic alcs. than E-trisubstituted compds.
Place, publisher, year, edition, pages
2011. Vol. 17, 11143-11145 p.
Research subject Organic Chemistry
IdentifiersURN: urn:nbn:se:su:diva-122304DOI: 10.1002/chem.201101524OAI: oai:DiVA.org:su-122304DiVA: diva2:865633