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Copper-Catalyzed Cross-Coupling of Allylboronic Acids with alpha-Diazoketones
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
2015 (English)In: Organic Letters, ISSN 1523-7060, E-ISSN 1523-7052, Vol. 17, no 19, 4754-4757 p.Article in journal (Refereed) Published
Abstract [en]

Copper-catalyzed cross-coupling of substituted allylboronic acids with alpha-diazoketones was studied. This allylation reaction is highly regioselective, providing the branched allylic product. The process involves creation of a new C(sp(3))-C(sp(3)) bond by retaining the keto functional group of the alpha-diazoketone precursor.

Place, publisher, year, edition, pages
American Chemical Society (ACS), 2015. Vol. 17, no 19, 4754-4757 p.
National Category
Organic Chemistry
Identifiers
URN: urn:nbn:se:su:diva-122944DOI: 10.1021/acs.orglett.5b02285ISI: 000362384700027OAI: oai:DiVA.org:su-122944DiVA: diva2:868750
Funder
Swedish Research CouncilKnut and Alice Wallenberg Foundation
Available from: 2015-11-11 Created: 2015-11-11 Last updated: 2017-12-01Bibliographically approved

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Wang, DongBelhomme, Marie-CharlotteSzabó, Kálmán J.
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