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Lewis Acid Catalyzed Annulation of Nitrones with Oxiranes, Aziridines, and Thiiranes
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Materials and Environmental Chemistry (MMK).
Stockholm University, Faculty of Science, Department of Organic Chemistry.
2015 (English)In: Organic Letters, ISSN 1523-7060, E-ISSN 1523-7052, Vol. 17, no 18, 4506-4509 p.Article in journal (Refereed) Published
Abstract [en]

A highly selective Lewis acid catalyzed annulation of three-membered heterocycles with nitrones has been developed. Oxiranes, aziridines, and thiiranes were used as substrates for the synthesis of various six-membered heterocycles using Al or In catalysts. This catalytic protocol demonstrates a broad substrate scope and provides access to new structural motifs in high yields and in excellent selectivity under mild reaction conditions.

Place, publisher, year, edition, pages
American Chemical Society (ACS), 2015. Vol. 17, no 18, 4506-4509 p.
National Category
Chemical Sciences
Identifiers
URN: urn:nbn:se:su:diva-122328DOI: 10.1021/acs.orglett.5b02195ISI: 000361867800028OAI: oai:DiVA.org:su-122328DiVA: diva2:875759
Funder
Swedish Research CouncilLars Hierta Memorial FoundationKnut and Alice Wallenberg Foundation
Available from: 2015-12-01 Created: 2015-10-29 Last updated: 2017-12-01Bibliographically approved

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