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Highly Selective Cascade C-C Bond Formation via Palladium-Catalyzed Oxidative Carbonylation-Carbocyclization-Carbonylation-Alkynylation of Enallenes
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Number of Authors: 3
2015 (English)In: Journal of the American Chemical Society, ISSN 0002-7863, E-ISSN 1520-5126, Vol. 137, no 37, 11868-11871 p.Article in journal (Refereed) Published
Abstract [en]

A highly efficient palladium-catalyzed oxidative cascade reaction of enallenes undergoing overall four C-C bond formations has been developed. The insertion cascade proceeds via carbonylation carbocyclization carbonylation alkynylation involving sequential insertion of carbon monoxide, olefin, and carbon monoxide. Furthermore, different types of terminal alkynes and functionalized enallenes have been investigated and found to undergo the cascade reaction under mild reaction conditions.

Place, publisher, year, edition, pages
2015. Vol. 137, no 37, 11868-11871 p.
National Category
Chemical Sciences
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URN: urn:nbn:se:su:diva-122320DOI: 10.1021/jacs.5b06828ISI: 000361930000004OAI: oai:DiVA.org:su-122320DiVA: diva2:876125
Available from: 2015-12-02 Created: 2015-10-29 Last updated: 2015-12-02Bibliographically approved

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Zhu, CanYang, BinBäckvall, Jan-E.
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