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Controlled molecular reorientation enables strong cellulose fibers regenerated from ionic liquid solutions
Stockholm University, Faculty of Science, Department of Materials and Environmental Chemistry (MMK). Wallenberg Wood Science Center, Sweden.
Stockholm University, Faculty of Science, Department of Materials and Environmental Chemistry (MMK). Wallenberg Wood Science Center, Sweden.
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Number of Authors: 6
2015 (English)In: Polymer, ISSN 0032-3861, E-ISSN 1873-2291, Vol. 75, 119-124 p.Article in journal (Refereed) Published
Abstract [en]

Cellulose is difficult to solubilize and undergoes thermal decomposition prior to melting. In recent years ionic liquids have been evaluated as solvents of cellulose. In the regeneration process the non-solvent governs the resulting material's crystallinity. Water adsorbs to amorphous cellulose, acts as plasticizer and lowers the T-g, hence the degree of crystallinity will affect the potential strain induced reorientation. We prepared regenerated cellulose fibers form ionic liquid using different non-solvents. The influence of shear forces upon cellulose chain alignment during extrusion was simulated in silica based upon rheological measurements. The regenerated fibers had different physical, morphological and mechanical properties. Molecular re-orientation in fibers induced by mechanical strain, at humidities above the Tg, resulted in much improved mechanical properties with the Young's modulus reaching 23.4 +/- 0.8 GPa and the stress at break 504.6 +/- 51.9 MPa, which is comparable to commercially available cellulose fibers.

Place, publisher, year, edition, pages
2015. Vol. 75, 119-124 p.
Keyword [en]
Regenerated cellulose fibers, Ionic liquid, Mechanical properties, Reorientation
National Category
Chemical Sciences
Identifiers
URN: urn:nbn:se:su:diva-122312DOI: 10.1016/j.polymer.2015.08.035ISI: 000361879300015OAI: oai:DiVA.org:su-122312DiVA: diva2:876530
Available from: 2015-12-04 Created: 2015-10-29 Last updated: 2015-12-04Bibliographically approved

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Guccini, ValentinaSalazar-Alvarez, German
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Department of Materials and Environmental Chemistry (MMK)
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