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Combined heterogeneous metal/organic catalysts for eco-friendly synthesis
Stockholm University, Faculty of Science, Department of Organic Chemistry. Mid Sweden University, Sweden.
Number of Authors: 1
2015 (English)In: Pure and Applied Chemistry, ISSN 0033-4545, E-ISSN 1365-3075, Vol. 87, no 9-10, 1011-1019 p.Article in journal (Refereed) Published
Abstract [en]

The interplay and synergistic cooperation between homogeneous and heterogeneous catalyst systems is of utmost importance in nature. It is also applied in chemical synthesis. Here, it can allow for new reactivity, which is not possible by the employment of a single catalyst, and promote the catalysis of multiple transformations in a one-pot sequence. This could overall lead to novel reactions and the development of sustainable chemistry. In this context, a versatile and broad synergistic strategy for the selective synthesis of valuable molecules with variable complexity and under eco-friendly conditions is disclosed. It is based on integrated heterogeneous metal/organo multiple relay catalysis, which is performed in a single reaction vessel, and allows for the assembly of complex molecules (e.g., heterocycles and carbocycles) with up to three quaternary stereocenters in a highly enantioselective fashion from simple alcohols and air/O-2.

Place, publisher, year, edition, pages
2015. Vol. 87, no 9-10, 1011-1019 p.
Keyword [en]
aerobic oxidations, asymmetric synthesis, biomaterials, biomimetic, biomimetic synthesis, carbocycles, cascade reactions, chemistry, eco-friendly synthesis, green chemistry, NICE-2014, selectivity
National Category
Chemical Sciences
Identifiers
URN: urn:nbn:se:su:diva-123807DOI: 10.1515/pac-2015-0405ISI: 000364625400008OAI: oai:DiVA.org:su-123807DiVA: diva2:881568
Available from: 2015-12-11 Created: 2015-12-07 Last updated: 2015-12-11Bibliographically approved

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